Polymers under nanoconfinement: where are we now in understanding local property changes?

Abstract

changes near interfaces, comparing across different types of interfaces: free surface, substrate, liquid, and polymer-polymer. Local versus film-average properties in thin films are discussed, making connections to other related property changes, while highlighting several historically important studies. By experimental necessity, most studies are on high enough molecule weight chains to be well entangled, although aspects that connect to lower molecule weight materials are described. Emphasis is made to identify observations and open questions that have yet to be fully understood such as the evidence of long-ranged interfacial effects, finite domain size, interfacial breadth, and chain connectivity.

Topics & Concepts