A radical mixed-ligand gold bis(dithiolene) complex
R. Perochon, Frédéric Barrière, Olivier Jeannin, L. Piekara-Sady, Marc Fourmigué
Abstract
A mixed-ligand bis(dithiolene) gold complex is isolated from scrambling reaction of two neutral radical symmetric complexes. Its asymmetric character translates into specific structural and electronic properties including larger electrochemical and optical band gaps than those of both precursors.
Topics & Concepts
AsymmetryElectrochemistryLigand (biochemistry)ChemistryCrystallographyMaterials sciencePhysicsElectrodePhysical chemistryBiochemistryReceptorQuantum mechanicsOrganic and Molecular Conductors ResearchMagnetism in coordination complexesPerovskite Materials and Applications