Triptycene-supported bimetallic salen porous organic polymers for high efficiency CO<sub>2</sub> fixation to cyclic carbonates
Yingting Zheng, Xiqian Wang, Chao Liu, Baoqiu Yu, Wenliang Li, Hailong Wang, Tingting Sun, Jianzhuang Jiang
Abstract
Triptycene units in bimetallic salen POPs are envisaged to support the alignment of bimetallic salen macrocycles in side walls of channels for exposing more metal active sites resulting in the high efficiency coupling reaction of epoxides with CO<sub>2</sub>.
Topics & Concepts
Bimetallic stripTriptycenePolymer chemistryMaterials scienceChemistryPolymerPorosityChemical engineeringMetalOrganic chemistryEngineeringCarbon dioxide utilization in catalysisCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and Applications