Spin transitions in ferric catecholate complexes mediated by outer-sphere counteranions
Maxim G. Chegerev, Олег П. Демидов, Pavel N. Vasilyev, Nikolay N. Efimov, S. P. Kubrin, А. Г. Стариков, В. Г. Власенко, Alexandr V. Piskunov, Svetlana Shapovalova, Alexander A. Guda, Yury V. Rusalev, А. В. Солдатов
Abstract
anions was found to demonstrate valence tautomeric transition along with spin-crossover. This finding makes compound 4 the first salt-like mononuclear ferric catecholate complex exhibiting valence tautomerism.
Topics & Concepts
ChemistrySpin crossoverCrystallographyTautomerElectron paramagnetic resonanceValence (chemistry)FerricSpin transitionIonic bondingSolventHyperfine structureLigand (biochemistry)Amine gas treatingInorganic chemistryStereochemistryIonNuclear magnetic resonanceOrganic chemistryBiochemistryQuantum mechanicsPhysicsReceptorMagnetism in coordination complexesLanthanide and Transition Metal ComplexesMetal-Catalyzed Oxygenation Mechanisms