Unraveling the Impact of Graphene Addition to Thermoelectric SrTiO<sub>3</sub> and La-Doped SrTiO<sub>3</sub> Materials: A Density Functional Theory Study
Joshua S. Tse, Alex Aziz, Joseph M. Flitcroft, Jonathan M. Skelton, Lisa J. Gillie, Stephen C. Parker, David J. Cooke, Marco Molinari
Abstract
surfaces, respectively. We find that graphene introduces C 2p states at the Fermi level, rendering the composite semimetallic, and thus the electrical properties are predicted to be highly sensitive to the amount and quality of the graphene. An investigation of the lattice dynamics predicts that graphene adsorption may lead to a 60-90% reduction in the thermal conductivity due to a reduction in the phonon group velocities, accounting for the reduced thermal conductivity of the composite materials observed experimentally. This effect is enhanced by La doping. We also find evidence that both La dopant ions and adsorbed graphene introduce low-frequency modes that may scatter heat-carrying acoustic phonons, and that, if present, these effects likely arise from stronger phonon-phonon interactions.