Functionalization of <i>o</i>-carboranes <i>via</i> carboryne intermediates
Zaozao Qiu, Zuowei Xie
Abstract
C-H bond and N-Li bond insertion reactions, which has not been observed for benzyne. This review provides a comprehensive overview of recent advances in this interesting research field with considerable attention devoted to the reaction modes and the mechanisms involved.
Topics & Concepts
ArynePericyclic reactionSynthonChemistryCarboraneRegioselectivitySteric effectsCombinatorial chemistryStereochemistryComputational chemistryMedicinal chemistryOrganic chemistryCatalysisBoron Compounds in ChemistryRadiopharmaceutical Chemistry and ApplicationsBoron and Carbon Nanomaterials Research