Second-sphere hydrogen-bonding enhances heterogeneous electrocatalytic CO<sub>2</sub> to CO reduction by iron porphyrins in water
Chanjuan Zhang, Diana Dragoé, François Brisset, Bernard Boitrel, Benedikt Lassalle‐Kaiser, Winfried Leibl, Zakaria Halime, Ally Aukauloo
Abstract
The export of second coordination effects from homogeneous to heterogeneous catalysis through catalyst immobilization on the surface of an electrode greatly boosts the catalytic performances for CO 2 electroreduction in water.
Topics & Concepts
CatalysisHomogeneousChemistryElectrochemistryInorganic chemistryElectrocatalystElectrodeHydrogen bondHydrogenHeterogeneous catalysisChemical engineeringPhysical chemistryMoleculeOrganic chemistryEngineeringThermodynamicsPhysicsCO2 Reduction Techniques and CatalystsCovalent Organic Framework ApplicationsElectrocatalysts for Energy Conversion