<scp>Well‐Designed</scp> Chiral Ligands for Enantioselective <scp>Ir‐Catalyzed</scp> C(sp<sup>2</sup>)–H Borylation<sup>†</sup>
Yin‐Xia Wang, P. Zhang, Mengchun Ye
Abstract
Due to the lack of proper chiral ligands, enantioselective C(sp 2 )–H borylation has been a challenging goal for a long time. Recently, three different types of well‐designed chiral ligands were developed, not only addressing this challenge, but also providing a good inspiration for the future development of other asymmetric reactions.
Topics & Concepts
ChemistryEnantioselective synthesisBorylationCatalysisStereochemistryCombinatorial chemistryOrganic chemistryAlkylArylCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistryAsymmetric Hydrogenation and Catalysis