Cycloaddition of isoselenocyanates to sodium and magnesium metallacycles
Vladimir A. Dodonov, Olga A. Kushnerova, Roman V. Rumyantsev, Alexander S. Novikov, В. К. Османов, Igor L. Fedushkin
Abstract
] (11, 12), which undergo fast decomposition at room temperature. New compounds are characterized by NMR, EPR, and IR spectroscopy, and elemental and X-ray diffraction analysis. Their electronic structures and reaction pathways were probed using DFT calculations.
Topics & Concepts
MagnesiumMetallacycleCycloadditionChemistryAcenaphtheneProtonationMedicinal chemistrySodiumDecompositionStereochemistryX-ray crystallographyCatalysisOrganic chemistryDiffractionNaphthalenePhysicsIonOpticsOrganometallic Complex Synthesis and CatalysisSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and Organometallics