Dual NHC/photoredox catalytic synthesis of 1,4-diketones using an MR-TADF photocatalyst (DiKTa)
Callum Prentice, J. A. Morrison, Eli Zysman‐Colman, Andrew D. Smith
Abstract
The use of the recently reported organic multi-resonant thermally activated delayed fluorescent (MR-TADF) photocatalyst DiKTa allows for the modular synthesis of 1,4-diketones under mild and metal-free conditions.
Topics & Concepts
CatalysisPhotocatalysisChemistryCarbenePhotochemistryFluorescenceComponent (thermodynamics)Combinatorial chemistryModular designOrganic chemistryOperating systemPhysicsThermodynamicsComputer scienceQuantum mechanicsCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques