Inverted and fused expanded heteroporphyrins
Rima Sengupta, Mangalampalli Ravikanth, Tavarekere K. Chandrashekar
Abstract
-inverted expanded heteroporphyrins and (2) hetero-atom inverted expanded heteroporphyrins. Both inverted expanded heteroporphyrins show quite unique features in terms of their structure, aromaticity, and electronic and coordination properties. Sometimes, inverted expanded heteroporphyrins lead to the formation of fused expanded heteroporphyrins because of the intramolecular fusion of the pyrrole "N" with the "C" of the inverted heterocycle ring, which also exhibit unique features compared to inverted expanded heteroporphyrins. In this review, we attempt to describe the synthesis, structure, and aromatic, electronic and coordination properties of inverted and fused expanded heteroporphyrins. This review covers the synthesis, structure and properties of inverted and fused expanded heteroporphyrins containing a combination of pyrrole/heterocycle rings starting with five pyrrole/heterocycle-containing pentaphyrins, and then expanded heteroporphyrins containing six, seven, eight and more pyrrole/heterocyclic rings in their porphyrin macrocyclic framework.