Electron Paramagnetic Resonance for the Detection of Electrochemically Generated Hydroxyl Radicals: Issues Associated with Electrochemical Oxidation of the Spin Trap
Emily Braxton, David J. Fox, Ben G. Breeze, Joshua J. Tully, Katherine J. Levey, Mark E. Newton, Julie V. Macpherson
Abstract
-butylnitrone, and 2-methyl-2-nitrosopropane dimer, also show electrochemical oxidation signals less positive than that of water on a BDD electrode. Such behavior also complicates their use for the intended application.
Topics & Concepts
ChemistryElectron paramagnetic resonanceRadicalElectrochemistryAdductSpin trappingAqueous solutionOxideInorganic chemistryOxidizing agentPhotochemistryElectrodeAnalytical Chemistry (journal)Nuclear magnetic resonancePhysical chemistryOrganic chemistryPhysicsElectron Spin Resonance StudiesAnalytical Chemistry and SensorsElectrochemical Analysis and Applications