Nickel supported on carbon nanotubes and carbon nanospheres for ammonia oxidation reaction
Marlén Alexis González-Reyna, María Selene Luna-Martínez, J.F. Pérez‐Robles
Abstract
Abstract Here it is proposed the use of nickel supported on carbon nanotubes and carbon nanospheres as a cheaper catalyst alternative to the platinum electrodes for the oxidation process of ammonia. Using scanning electron microscopy and Raman spectroscopy confirmed the presence of the Ni on the surface of the carbon nanostructures and based on the electrochemical results is established that the redox process between Ni +2 and Ni +3 plays the role of intermediate in the ammonia oxidation reaction. This process causes an increment in the anodic current density that is dependent on the pH and ammonia concentration. Even more, using the rotating disk electrode technique, the ammonia oxidation, is defined as a diffusion-controlled process that follows first-order kinetics in respect of the concentration of ammonia and suggests the formation of nitrogen as the principal reaction product, where the carbon nanospheres present the best results.