Iron(<scp>ii</scp>) coordination pyrazole complexes with aromatic sulfonate ligands: the role of ether
Varun Kumar, Mohamed El Massaoudi, Smaail Radi, Kristof Van Hecke, Aurelian Rotaru, Yann Garcia
Abstract
Diethyl ether altered the usual homoleptic FeN<sub>6</sub> self-assembly of Fe(<sc>ii</sc>) mononuclear complexes to yield an FeN<sub>4</sub>O<sub>2</sub> heteroleptic coordination environment.
Topics & Concepts
ChemistryHomolepticPyrazoleEtherCoordination complexLigand (biochemistry)Medicinal chemistryYield (engineering)StereochemistrySulfonateMetalOrganic chemistryReceptorBiochemistrySodiumMetallurgyMaterials scienceMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesMetal complexes synthesis and properties