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Photochemical selective difluoroalkylation reactions of bicyclobutanes: direct sustainable pathways to functionalized bioisosteres for drug discovery

Yunxin Duan, Yerong Xu, Yunzhe Li, Lin Mao, Jianquan Feng, Jianquan Feng, Ruyue Zhang, Weifang Tang, Tao Lu, Yadong Chen, Jie Feng, Jie Feng

2024Green Chemistry23 citationsDOI

Abstract

Photochemical solvent-controlled difluoromethylation and bromo-difluoromethylation reactions of bicyclobutanes are described. The method provides efficient pathways to obtain difluoroalkyl functionalized bioisosteres for drug discovery.

Topics & Concepts

Drug discoveryChemistryCombinatorial chemistryDrugPharmacologyBiologyBiochemistryFluorine in Organic ChemistryClick Chemistry and ApplicationsChemical Synthesis and Analysis