An NADH-Inspired Redox Mediator Strategy to Promote Second-Sphere Electron and Proton Transfer for Cooperative Electrochemical CO <sub>2</sub> Reduction Catalyzed by Iron Porphyrin
Peter T. Smith, Sophia Weng, Christopher J. Chang
Abstract
reduction, providing a starting point for broader applications of this approach to other multielectron, multiproton transformations.
Topics & Concepts
ChemistryRedoxElectron transferCatalysisElectrochemistryPorphyrinProton-coupled electron transferProtonCombinatorial chemistryElectron transport chainPhotochemistryInorganic chemistryOrganic chemistryPhysical chemistryElectrodeQuantum mechanicsBiochemistryPhysicsCO2 Reduction Techniques and CatalystsAdvanced battery technologies researchElectrocatalysts for Energy Conversion