Efficient synthesis of tetrahydrofurans with chiral tertiary allylic alcohols catalyzed by Ni/<i>P</i>-chiral ligand DI-BIDIME
Yu Mu, Tao Zhang, Yaping Cheng, Wen‐Zhen Fu, Zuting Wei, Wanjun Chen, Guodu Liu
Abstract
Efficient nickel-catalyzed stereoselective asymmetric intramolecular reductive cyclization of <italic>O</italic>-alkynones with <italic>P</italic>-chiral bisphosphorus ligand DI-BIDIME is reported.
Topics & Concepts
StereoselectivityLigand (biochemistry)CatalysisIntramolecular forceChemistryAllylic rearrangementStereochemistryChiral ligandMedicinal chemistryEnantioselective synthesisCombinatorial chemistryOrganic chemistryReceptorBiochemistryCatalytic C–H Functionalization MethodsSynthetic Organic Chemistry MethodsCyclopropane Reaction Mechanisms