Interface Engineering of NiMoS<i><sub>x</sub></i>@NiMnFe Prussian Blue Analogue Nanowires to Efficiently Boost Overall Seawater Splitting at High Current Densities
Pan Wang, Pai Wang, Tongwei Wu, Changlu Zhao, Zonghua Pu, Yanning Zhang
Abstract
Abstract Developing high‐activity and robust‐stability electrocatalysts for hydrogen production at high current densities from seawater remains a big challenge owing to chloride corrosion and electrochemical damage at high potentials. Herein, 3D core–shell nanowires of NiMoS x @NiMnFe Prussian blue analogue (NiMoS x @NiMnFe‐PBA) are rationally designed and prepared, exhibiting excellent oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) activities in alkaline seawater with low overpotentials of 260 and 71 mV at 10 mA cm −2 , respectively. Surprisingly, as a bifunctional electrocatalyst for overall seawater splitting, it needs a low cell voltage of 1.513 V at 10 mA cm −2 with an ultrahigh stability of 2500 h at 500 mA cm −2 , implying potential commercial applications. Both experimental and theoretical results signify its lattice oxygen mechanism pathway for OER, where the Fe and Mn efficiently decrease energy barriers to facilitate the OER kinetics. Moreover, the formed heterostructures via interface engineering create abundant active sites and facilitate rapid kinetics, while the 3D structure provides many active sites. The NiMnFe‐PBA as a protective shell prevents the core of NiMoS x from fast anodic oxidation damage and guarantees high chloride‐corrosion resistance by the repelling‐chloride characteristic. Accordingly, this work sheds light on developing excellent seawater‐splitting electrocatalysts at high current densities.