Magnetic anisotropy and structural flexibility in the field-induced single ion magnets [Co{(OPPh<sub>2</sub>)(EPPh<sub>2</sub>)N}<sub>2</sub>], E = S, Se, explored by experimental and computational methods
Eleftherios Ferentinos, Demeter Tzeli, Silvia Sottini, E. J. J. Groenen, Mykhaylo Ozerov, Giordano Poneti, Kinga Kaniewska-Laskowska, J. Krzystek, Panayotis Kyritsis
Abstract
, they exhibit slow relaxation of magnetization in the presence of an external DC magnetic field. Advanced quantum-chemical calculations on CoO2E2 provided additional insight into their electronic and structural properties.
Topics & Concepts
TetrahedronMagnetAnisotropyIonMaterials scienceField (mathematics)Magnetic anisotropyMagnetic fieldFlexibility (engineering)Condensed matter physicsAtomic physicsCrystallographyPhysicsNanotechnologyChemistryMagnetizationOpticsQuantum mechanicsMathematicsStatisticsPure mathematicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research