Litcius/Paper detail

Phototransferred thermoluminescence of BeO: Time-response profiles and mechanisms

M.L. Chithambo, J.M. Kalita

2021Journal of Applied Physics17 citationsDOI

Abstract

Phototransferred thermoluminescence (PTTL) from BeO is reported. The conventional TL glow curve has five peaks, I–V, at 50, 182, 283, 437, and 535 °C when measured at 1 °C s−1 The dominant one is peak II. Only the first three reappear under phototransfer. Electron traps for peaks IV and V weakly contribute to the PTTL. The PTTL at peak III, supposedly associated with these weak donors, is counterintuitively intense. All PTTL peaks are affected by light-induced fading, thermal quenching, and all but peak II by thermal fading. The activation energy for thermal quenching was found as 0.56±0.02, 0.53±0.05, and 0.94±0.07eV using peaks I, II, and III, respectively. Electronic processes relevant in the PTTL of BeO are discussed. PTTL time-response profiles are analyzed using systems of coupled linear differential equations as well as by theoretical modeling.

Topics & Concepts

ThermoluminescenceActivation energyAnalytical Chemistry (journal)Quenching (fluorescence)ChemistryMaterials scienceLuminescencePhysical chemistryFluorescencePhysicsOptoelectronicsOpticsChromatographySpectroscopy and Laser ApplicationsLuminescence Properties of Advanced MaterialsAdvanced Chemical Physics Studies