Litcius/Paper detail

Palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with sulfonamido-substituted acyclic allylic carbonates

Han-Wen Rao, Tian-lan Zhao, Long Wang, Hongdan Deng, Yan-Ping Zhang, Yong You, Zhen‐Hua Wang, Jian‐Qiang Zhao, Wei‐Cheng Yuan

2023Organic & Biomolecular Chemistry16 citationsDOI

Abstract

generated from sulfonamido-substituted allylic carbonates, is successfully developed. This method allows the formation of a series of structurally diverse 5-alkylated thiazolidinones and 2-piperidones under mild conditions in moderate to high yields (up to 99% yield).

Topics & Concepts

ChemistryAllylic rearrangementPalladiumCatalysisYield (engineering)Tsuji–Trost reactionOrganic chemistryCombinatorial chemistryMetallurgyMaterials scienceCatalytic C–H Functionalization MethodsFluorine in Organic ChemistryAsymmetric Synthesis and Catalysis
Palladium-catalyzed decarboxylative α-allylation of thiazolidinones and azlactones with sulfonamido-substituted acyclic allylic carbonates | Litcius