The template effect of a SiF<sub>6</sub><sup>2−</sup>guest drives the formation of a heteroleptic Fe(<scp>ii</scp>) coordination helicate
Nuria Capó, Leoní A. Barrios, Joan Cardona, Jordi Ribas‐Ariño, Simon J. Teat, Olivier Roubeau, Guillem Aromı́
Abstract
exerts a strong template effect, driving the exclusive assembly of two different bispyridylpyrazolyl ligands into a triple stranded Fe(II) dinuclear heteroleptic helicate, engendering a new class within the large family of coordination helicates.
Topics & Concepts
ChemistryCrystallographyStereochemistryNanotechnologyCombinatorial chemistryMaterials scienceMagnetism in coordination complexesPorphyrin and Phthalocyanine ChemistryLanthanide and Transition Metal Complexes