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Recent Advances in Non-Noble Metal Electrocatalysts for Hydrogen Evolution Reaction in Water Splitting

Aiyi Dong, Zifeng Li, Yinhua Ma, Wanyi Liao, Fengjiao Zhao, Xun Zhang, Honglin Gao

2025Nanomaterials29 citationsDOIOpen Access PDF

Abstract

Electrochemical water splitting is an efficient and eco-friendly method for hydrogen production, offering a sustainable energy solution. Currently, the noble metal platinum is considered to be the most efficient catalyst for electrochemical hydrogen evolution reactions (HERs). Due to the scarcity and high cost of noble metal materials, there is an urgent need to find abundant and cost-effective non-noble metal catalysts to reduce the overpotential of HERs. In recent years, significant scientific advancements have been reported in non-noble metal HER catalysts. This review categorizes and reviews the recent non-noble metal HER catalysts and their reaction mechanisms. An exhaustive overview of proven effective catalyst categories is provided, offering early-career researchers a panoramic understanding of this dynamic research field. Finally, we address current challenges and future directions in this field to encourage further research efforts and the development of non-noble metal catalysts.

Topics & Concepts

Noble metalOverpotentialWater splittingCatalysisHydrogen productionPlatinumNanotechnologyMaterials sciencePrecious metalElectrochemistryChemistryPhotocatalysisPhysical chemistryBiochemistryElectrodeElectrocatalysts for Energy ConversionAdvanced Photocatalysis TechniquesElectrochemical Analysis and Applications