Efficient (<i>Z</i>)-selective semihydrogenation of alkynes catalyzed by air-stable imidazolyl amino molybdenum cluster sulfides
María Gutiérrez‐Blanco, Eva Guillamón, Vicent S. Safont, Andrés G. Algarra, M. Jesús Fernández‐Trujillo, Kathrin Junge, Manuel G. Basallote, Rosa Llusar, Matthias Beller
Abstract
Efficient protocols for the semihydrogenation of internal alkynes and terminal alkynols are reported using the new [Mo 3 S 4 Cl 3 (ImNH 2 ) 3 ] + complex as catalyst.
Topics & Concepts
CatalysisMolybdenumCluster (spacecraft)ChemistryCombinatorial chemistryMedicinal chemistryPolymer chemistryOrganic chemistryComputer scienceProgramming languageInorganic Chemistry and MaterialsCarbon dioxide utilization in catalysisMetalloenzymes and iron-sulfur proteins