Separation of High-Purity C<sub>2</sub>H<sub>2</sub> from Binary C<sub>2</sub>H<sub>2</sub>/CO<sub>2</sub> Using Robust Al-Based MOFs Comprising Nitrogen-Containing Heterocyclic Dicarboxylate
Se‐Min Jeong, Dong-Hyun Kim, Ju Yeon Park, Ji Woong Yoon, Su‐Kyung Lee, Jong Suk Lee, Donghui Jo, Kyung Ho Cho, U‐Hwang Lee
Abstract
In this study, three nitrogen-containing aluminum-based metal–organic frameworks (Al-MOFs), namely, CAU-10pydc, MOF-303, and KMF-1, were investigated for the efficient separation of a C 2 H 2 /CO 2 gas mixture. Among these three Al-MOFs, KMF-1 demonstrated the highest selectivity for C 2 H 2 /CO 2 separation (6.31), primarily owing to its superior C 2 H 2 uptake (7.90 mmol g –1 ) and lower CO 2 uptake (2.82 mmol g –1 ) compared to that of the other two Al-MOFs. Dynamic breakthrough experiments, using an equimolar binary C 2 H 2 /CO 2 gas mixture, demonstrated that KMF-1 achieved the highest separation performance. It yielded 3.42 mmol g –1 of high-purity C 2 H 2 (>99.95%) through a straightforward desorption process under He purging at 298 K and 1 bar. To gain insights into the distinctive characteristics of the pore surfaces of structurally similar CAU-10pydc and KMF-1, we conducted computational simulations using canonical Monte Carlo and dispersion-corrected density functional theory methods. These simulations revealed that the secondary amine (C 2 N–H) groups in KMF-1 played a more significant role in differentiating between C 2 H 2 and CO 2 compared to that of the N atoms in CAU-10pydc and MOF-303. Consequently, KMF-1 emerged as a promising adsorbent for the separation of high-purity C 2 H 2 from binary C 2 H 2 /CO 2 gas mixtures.