Band gap modulation of organic–inorganic Sb(<scp>iii</scp>) halide by molecular design
Yanning Wang, Liang Tong, Min-Wan, Jing-Yuan Liu, Siyu Ye, Abraham Mensah, Jun‐Yi Li, Li-Zhuang Chen
Abstract
Four organic–inorganic hybrid materials were designed, and a successful adjustment of the band gap was obtained, from 2.933 eV to as low as 2.788 eV, via replacing the third hydrogen atom of the benzene ring in the organic cation with a halogen.
Topics & Concepts
HalogenHalideBenzeneBand gapChemistryRing (chemistry)Atom (system on chip)Inorganic chemistryMaterials scienceOrganic chemistryOptoelectronicsComputer scienceEmbedded systemAlkylPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyCrystal Structures and Properties