Halohydroxylation of alkenyl MIDA boronates: switchable stereoselectivity induced by B(MIDA) substituent
Yao‐Fu Zeng, Xu‐Ge Liu, Dong‐Hang Tan, Wen‐Xin Fan, Yina Li, Yu Guo, Honggen Wang
Abstract
A switchable stereoselectivity in the halohydroxylation of alkenyl MIDA boronates was found. C–B(MIDA) bond hyperconjugation plays the key role.
Topics & Concepts
StereoselectivitySubstituentChemistryStereochemistryOrganic chemistryCatalysisCatalytic C–H Functionalization MethodsVanadium and Halogenation ChemistryChemical Synthesis and Reactions