Litcius/Paper detail

Ligand engineering of circularly polarized luminescence inversion and enhancement for chiral Ag<sub>6</sub> nanoclusters

Hui Chen, Xiangyang Zhang, Kuo Fu, Xuejuan Wang, Guofeng Liu

2024Journal of Materials Chemistry C10 citationsDOIOpen Access PDF

Abstract

Four pairs of chiral Ag 6 L 6 nanoclusters, synthesized using ligand engineering with thiazithione and oxazinthione, exhibit enhanced luminescence quantum yield attributed to S⋯S interactions and demonstrate supramolecular chirality inversion regulated by peripheral methyl and phenyl groups.

Topics & Concepts

NanoclustersLuminescenceMaterials scienceChirality (physics)Supramolecular chemistryLigand (biochemistry)Supramolecular chiralityQuantum yieldCrystallographyPhotochemistryNanotechnologyOptoelectronicsOpticsCrystal structureChemistryFluorescencePhysicsChiral symmetry breakingQuantum mechanicsBiochemistryNambu–Jona-Lasinio modelReceptorQuarkNanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and ApplicationsSupramolecular Self-Assembly in Materials