Highly proton-conducting lanthanide metal–organic frameworks featuring highly oxygenated ligands with slow magnetic relaxation or magnetocaloric effect
Shun-Yi Yang, Qian Zhang, Yang-Lu Zhang, Tie-Shen Tan, Junlun Zhu, Xiaodong Yang, Le Shi, Jiong Yang, Dong Shao
Abstract
Two Tb( iii ) and Gd( iii ) MOFs synthesized through a hydroxy-functionalized dicarboxybenzene were reported to show conductivities up to the 10 −2 S cm −1 level with slow magnetic relaxation and magnetocaloric effect.
Topics & Concepts
LanthanideMagnetic refrigerationMagnetic relaxationProtonMetalMetal-organic frameworkMaterials scienceRelaxation (psychology)Combinatorial chemistryNanotechnologyInorganic chemistryChemical engineeringChemical physicsPhysical chemistryChemistryOrganic chemistryMagnetic fieldPhysicsMetallurgyMagnetizationNuclear physicsIonPsychologySocial psychologyQuantum mechanicsEngineeringAdsorptionMagnetism in coordination complexesMetal-Organic Frameworks: Synthesis and ApplicationsLanthanide and Transition Metal Complexes