One-pot hydrothermal synthesis of transition metal sulfides-decorated CuS microflower-like structures for electrochemical CO2 reduction to CO
Yafei Guo, Yuxuan Gao, Benshuai Guo, Yangna Luo, Guoyang Zhao, Jian Sun, Weiling Li, Ruilin Wang, Chuanwen Zhao
Abstract
Abstract Electrochemical CO 2 reduction (ECR) to value-added products is regarded as a sustainable strategy to mitigate global warming and energy crisis, and designing highly efficient and robust catalysts is essential. In this work, transition metal sulfides (TMS)-decorated CuS microflower-like structures were prepared via the one-pot hydrothermal synthesis method for ECR to CO, and the influence of TMS doping on ECR performance was demonstrated. Characterization of the catalysts was performed using XRD, FESEM-EDS, N 2 physisorption, and XPS, revealing the successful loading of TMS, the formation of microflower-like architectures and the generation of sulfur vacancies. Electrochemical tests demonstrated that doping ZnS, Bi 2 S 3 , CdS and MoS 2 improved the intrinsic CO 2 reduction activity of the CuS catalyst. Particularly, the MoS 2 -CuS composite catalyst with imperfect petal-like structure showed uniform distribution of edge Mo sites, which worked synergistically with the formed grain boundaries (GBs) and undercoordinated S vacancy sites in promoting CO 2 activation, stabilizing * COOH adsorption, facilitating * CO desorption, and lowering the energy barrier of the potential-limiting step for improved CO selectivity. The MoS 2 -CuS catalyst achieved a maximum CO selectivity of 83.2% at –0.6 V versus the reversible hydrogen electrode (RHE) and a high CO cathodic energetic efficiency of 100%. At this potential, the catalyst maintained stable catalytic activity and CO selectivity during a 333-min electrolysis process. The findings will offer a promising avenue for the development of efficient and stable catalysts for CO production from ECR.