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Expansion counteraction effect assisted vanadate with rich oxygen vacancies as a high cycling stability cathode for aqueous zinc-ion batteries

Xiao-Luan Xie, Yifan Li, Cheng Wang, Da‐Wei Gu, Lei Wang, Qiao Qiao, Yang Zou, Zhi-Yuan Yao, Linjiang Shen, Xiaoming Ren

2025Physical Chemistry Chemical Physics7 citationsDOI

Abstract

with a capacity retention of 95.5% after 2100 cycles. This study not only provides a novel approach for synthesizing nanoscale vanadate cathodes with rich oxygen vacancies, but also proposes the "expansion counteraction effect" theory, offering innovative insights into the design of high cycling stability cathodes for AZIBs.

Topics & Concepts

VanadateCathodeCyclingAqueous solutionMaterials scienceOxygenIonOxygen evolutionChemical engineeringChemistryInorganic chemistryElectrochemistryElectrodeMetallurgyPhysical chemistryArchaeologyOrganic chemistryHistoryEngineeringAdvanced battery technologies researchCopper-based nanomaterials and applicationsElectronic and Structural Properties of Oxides
Expansion counteraction effect assisted vanadate with rich oxygen vacancies as a high cycling stability cathode for aqueous zinc-ion batteries | Litcius