Photoredox‐Promoted Co‐Production of Dihydroisoquinoline and H<sub>2</sub>O<sub>2</sub> over Defective Zn<sub>3</sub>In<sub>2</sub>S<sub>6</sub>
Juanjuan Luo, Xinfa Wei, Qiao Yang, Chenyao Wu, Lanxin Li, Lisong Chen, Jianlin Shi
Abstract
Abstract One of the most sustainable and promising approaches for hydrogen peroxide (H 2 O 2 ) production in a low‐cost and environment‐friendly way is photosynthesis, which, however, suffers from poor carrier utilization and low H 2 O 2 productivity. The addition of proton donors such as isopropanol or ethanol can increase H 2 O 2 production, which, unfortunately, will inevitably elevate the entire cost while wasting the oxidizing power of holes (h + ). Herein, the tetrahydroisoquinolines (THIQs) is employed as a distinctive proton donor for the thermodynamically feasible and selective semi‐dehydrogenation reaction to highly valuable dihydroisoquinolines (DHIQs), and meanwhile, to couple with and promote H 2 O 2 generation in one photoredox reaction under the photocatalysis by dual‐functional Zn 3 In 2 S 6 photocatalyst. Surprisingly, the suitably defective Zn 3 In 2 S 6 offers an excellent and near‐stoichiometric co‐production performance of H 2 O 2 and DHIQs at unprecedentedly high rates of 66.4 and 62.1 mmol h ‐1 g ‐1 under visible light (λ ≥ 400 nm), respectively, which outperforms all the previously available reports even though sacrificial agents were employed in those reports. Additionally, photocatalytic redox reaction mechanism demonstrates that H 2 O 2 can be generated through multiple pathways, highlighting the synergistic effect among ROS (·O 2 ‐ and 1 O 2 ), h + and proton donor, which has been ignored in previous studies.