Revealing redox isomerism in trichromium imides by anomalous diffraction
Amymarie K. Bartholomew, Rebecca A. Musgrave, Kevin J. Anderton, Cristin E. Juda, Yuyang Dong, Wei Bu, SuYin Grass Wang, Yu‐Sheng Chen, Theodore A. Betley
Abstract
Application of high-resolution Multiwavelength Anomalous Diffraction (MAD) allows the assignment of localized, partly delocalized, and fully delocalized oxidation in a series of trichromium imide isomers.
Topics & Concepts
ImideChemistryRedoxDelocalized electronCrystallographyAdductPhotochemistryStereochemistryInorganic chemistryPolymer chemistryOrganic chemistryMetalloenzymes and iron-sulfur proteinsOrganometallic Complex Synthesis and CatalysisMetal-Catalyzed Oxygenation Mechanisms