HgB<sub>2</sub>S<sub>4</sub>: A <i>d</i><sup>10</sup> Metal Thioborate with Giant Birefringence and Wide Band Gap
Yi Huang, Yong Zhang, Dongdong Chu, Zhihua Yang, Guangmao Li, Shilie Pan
Abstract
Birefringent crystals are important optical devices in various advanced optical systems because they can create and control polarized light. In this work, the capability of planar [B 3 S 6 ] to produce large birefringence was theoretically studied for the first time. Moreover, the first d 10 metal thioborate HgB 2 S 4 (HBS) has been synthesized successfully, which was constructed by the π-conjugated [B 3 S 6 ] and [HgS 2 ] units. Notably, HBS shows great potential to be an infrared birefringent material due to its large birefringence, Δ n = 0.52 @ 1064 nm (∼4.3 × α-BaB 2 O 4 and ∼10.4 × AgGaS 2 @ 1064 nm), wide band gap of 3.36 eV, and wide transparent window (∼0.37–25 μm). To the best of our knowledge, both the birefringence and the band gap of HBS are the largest among mercury sulfides. Structure-performance analyses reveal that the π-conjugated [B 3 S 6 ] units are the main birefringence contributor and could be regarded as a good unit for designing IR birefringent materials. This work will provide direct guidance to design high performance birefringent crystals in the future.