Synthesis of Porphyrin Zr-MOFs for the Adsorption and Photodegradation of Antibiotics under Visible Light
Yuqing Zong, Shuaishuai Ma, Jiamin Gao, Minjing Xu, Jinjuan Xue, Mingxin Wang
Abstract
for TC and CIP, respectively. The adsorption of TC and CIP in 300 nm-PCN-224 is consistent with the pseudo-second-order kinetic model and Langmuir isotherm model, which indicates that the adsorption can be regarded as homogeneous monolayer chemisorption, and the adsorption is exothermic, which has been confirmed by thermodynamic studies. Under visible-light irradiation, 300 nm-PCN-224 exhibited high photocatalytic activity for TC and CIP. The adsorption studies confirmed that the adsorption of adsorbates takes place via the formation of hydrogen bonding, π-π interactions, and electrostatic attraction. In addition, the adsorbent can be simply regenerated by photocatalysis under visible light, and the adsorption-desorption efficiency is still above 85% after repeated use five times. The work of MOFs to remove antibiotics from water shows that MOFs have great potential in this field and are worthy of further study.