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Diaryl hypervalent bromines and chlorines: synthesis, structures and reactivities

Matteo Lanzi, Joanna Wencel‐Delord

2024Chemical Science27 citationsDOIOpen Access PDF

Abstract

-bromanes and -chloranes. Despite their unique reactivities, the progress in their development and application within organic synthesis has been hampered by the absence of straightforward, reliable, and widely applicable preparative methods. However, recent investigations have uncovered innovative approaches and novel reactivity patterns associated with these specialized compounds. These discoveries suggest that we have only begun to tap into their potential, implying that there is much more to be explored in this captivating area of chemistry.

Topics & Concepts

Hypervalent moleculeContext (archaeology)Foundation (evidence)ChemistryOrganic chemistryHistoryArchaeologyReagentOxidative Organic Chemistry ReactionsSynthesis and Catalytic ReactionsVanadium and Halogenation Chemistry