Organic Multiferroic Magnetoelastic Complexes
Mengmeng Wei, Kepeng Song, Yuying Yang, Qikun Huang, Yufeng Tian, Xiaotao Hao, Wei Qin
Abstract
The design of crystal structures aids the discovery of interesting physical phenomena in organic crystals. In this work, the optimization of the coronene-tetracyanoquinodimethane (TCNQ) structure generates non-degenerate energy levels of spin-up and spin-down electrons after charge transfer, producing spontaneous spin polarization, leading to pronounced ferromagnetism. The deformed crystal lattice can significantly affect the saturation magnetization of organic ferromagnets to present a remarkable magnetoelastic coupling. Furthermore, the magnetic-field-induced lattice shrinkage of the ferromagnetic crystals supports a spin-lattice-interaction-dependent magnetoelastic coupling. This concept of organic magnetoelastic coupling will pave the way for the rapid mechanical control of spin polarization in organic multiferroic magnetoelastic materials.