Synthesis of Anatase/Brookite Mixed Phase TiO <sub>2</sub> Nanostructures and its Photocatalytic Performance Study
Niteen S. Jawale, Sudhir S. Arbuj, Govind Umarji, Sunit Rane
Abstract
Abstract The TiO 2 nanostructures were prepared using hydrothermal reaction technique at different reaction temperatures viz., 120 °C, 160 °C, and 200 °C for 24 h. The synthesized TiO 2 nanostructures was characterised by various spectroscopic techniques. XRD indicate the formation of highly crystalline nano size particles of anatase phase of TiO 2 along with minor percentage of brookite phase. Diffuse reflectance UV‐Visible spectroscopy depicts the band gap around 3.2 eV. The FE‐SEM shows formation of spherical particles having size in the range of 5 to 10 nm, however the small particles tend to agglomerate leading to the formation of submicron size clusters. TEM analysis confirms the formation of nanostructured TiO 2 having size in the range of 5 to 10 nm with distorted spherical shaped morphology. The photocatalytic performance of the synthesized TiO 2 was investigated by observing the degradation of aqueous methylene blue (MB) dye and H 2 generation via water splitting under 400 W mercury vapour lamp respectively. Among the prepared samples, the TiO 2 prepared at 160 °C, showed highest MB degradation (97 %) within 1 h of irradiation time. The photocatalytic H 2 generation via water splitting was also investigated and found to be highest for TiO 2 prepared at 160 °C, the observed rate of H 2 generation was 3848 μmol/0.1 g in 4 h is almost twelve fold higher than the pure anatase phase.