Preparation and reactivity of molybdenum complexes bearing pyrrole-based PNP-type pincer ligand
Yoshiaki Tanabe, Yoshiya Sekiguchi, Hiromasa Tanaka, Asuka Konomi, Kazunari Yoshizawa, Shogo Kuriyama, Yoshiaki Nishibayashi
Abstract
Molybdenum complexes bearing an anionic pyrrole-based PNP-type pincer ligand have been prepared and have been found to work as catalysts for the conversion of N2 into NH3 under ambient conditions.
Topics & Concepts
MolybdenumPincer movementReactivity (psychology)Ligand (biochemistry)Pincer ligandPyrroleBearing (navigation)ChemistryCombinatorial chemistryPolymer chemistryStereochemistryMedicinal chemistryOrganic chemistryCatalysisComputer scienceBiochemistryReceptorMedicineArtificial intelligenceAlternative medicinePathologyAmmonia Synthesis and Nitrogen ReductionCatalytic Processes in Materials ScienceAsymmetric Hydrogenation and Catalysis