Importance of an Axial Ln<sup>III</sup>–F Bond across the Lanthanide Series and Single-Molecule Magnet Behavior in the Ce and Nd Analogues
Emma Regincós Martí, Angelos B. Canaj, Tanu Sharma, Anna Celmina, Claire Wilson, Gopalan Rajaraman, Mark Murrie
Abstract
-Nd and for promoting the SMM behavior. Importantly, this systematic study provides insight into the magnetic properties of these lighter lanthanide ions.
Topics & Concepts
LanthanideChemistrySingle-molecule magnetCrystallographyMagnetizationMoleculeRelaxation (psychology)Ligand (biochemistry)Magnetic relaxationMagnetAnisotropyLigand field theoryIonMagnetic fieldPhysicsSocial psychologyReceptorPsychologyOrganic chemistryQuantum mechanicsBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal Complexes