Mixed-Metal Cu-BTC Metal–Organic Frameworks as a Strong Adsorbent for Molecular Hydrogen at Low Temperatures
Abdul Malik P. Peedikakkal, Isam H. Aljundi
Abstract
to other metal ions. The higher charge density of metal ions strongly polarizes hydrogen and provides the primary binding sites inside the pores of Cu-BTC and subsequently enhances the gravimetric uptake of hydrogen.
Topics & Concepts
Metal-organic frameworkHydrogen storageGravimetric analysisMetalAdsorptionHydrogenIsostructuralInorganic chemistryThermogravimetric analysisMetal ions in aqueous solutionMaterials scienceChemistryCrystallographyCrystal structurePhysical chemistryMetallurgyOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsHydrogen Storage and MaterialsCarbon dioxide utilization in catalysis