Gating of Hydrophobic Nanopores with Large Anions
Jake W. Polster, Elif Türker Acar, Fikret Aydin, Cheng Zhan, Tuan Anh Pham, Zuzanna S. Siwy
Abstract
and consequently were prone to migrate from the aqueous solution to the hydrophobic surface, leading to the anion accumulation responsible for pore wetting. The results are essential for designing nanoporous systems that are selective to ions of the same charge, for realization of ion-induced wetting in hydrophobic pores, as well as for a fundamental understanding on the role of ion hydration shell on the properties of solid/liquid interfaces.
Topics & Concepts
NanoporeGatingNanotechnologyMaterials scienceBiophysicsBiologyNanopore and Nanochannel Transport StudiesMicrofluidic and Capillary Electrophoresis ApplicationsElectrostatics and Colloid Interactions