A synthetic strategy towards single crystals of Zr<sub>6</sub> cluster and phosphonate-based metal–organic frameworks
Haomiao Xie, Kent O. Kirlikovali, Zhijie Chen, Karam B. Idrees, Timur İslamoğlu, Omar K. Farha
Abstract
We developed a strategy for synthesizing single-crystal Zr-phosphonate MOFs, retaining parent topology via post-synthesis. SALE and post-synthetic oxidation enable linker modification, enhancing hydrophilicity and Brønsted acidity.
Topics & Concepts
PhosphonateCluster (spacecraft)ZirconiumMaterials scienceMetalMetal-organic frameworkCrystallographyNanotechnologyMineralogyChemistryMetallurgyPhysical chemistryComputer scienceOrganic chemistryAdsorptionProgramming languageMetal-Organic Frameworks: Synthesis and ApplicationsMXene and MAX Phase MaterialsInorganic Chemistry and Materials