Frustrated Lewis pair catalyzed hydrodehalogenation of benzyl-halides
Tongtong Wang, Maotong Xu, Andrew R. Jupp, Shi-Ming Chen, Zheng‐Wang Qu, Stefan Grimme, Douglas W. Stephan
Abstract
]. This species acts in analogy to a FLP to cooperatively activate C-X bond (X = Cl, Br, I) of benzyl-halides delivering hydride and generating the corresponding ammonium halide salts.
Topics & Concepts
HalideChemistryHalogenationTolueneCatalysisAmmoniumMedicinal chemistryHydridePolymer chemistryOrganic chemistryHydrogenOrganoboron and organosilicon chemistryBoron Compounds in ChemistryCatalytic Cross-Coupling Reactions