Litcius/Paper detail

Pore-scale imaging of asphaltene deposition with permeability reduction and wettability alteration

Yihuai Zhang, Qingyang Lin, Ali Q. Raeini, Yutaka Onaka, Hiroki Iwama, Katsumo Takabayashi, Martin J. Blunt, Branko Bijeljic

2022Fuel38 citationsDOIOpen Access PDF

Abstract

To better understand asphaltene deposition mechanisms and their influence on rock permeability and wettability, we have developed an in situ micro-CT imaging capability to observe asphaltene precipitation during multiphase flow at high resolution in three dimensions. Pure heptane and crude oil were simultaneously injected to induce asphaltene precipitation in the pore space of a sandstone rock sample. The heptane permeability across the sample was nine times lower after the first asphaltene precipitation, while it was reduced by a factor of ninety due to asphaltene migration and growth after subsequent brine injection. Furthermore, through quantifying the curvatures and contact angles on the images before and after asphaltene precipitation, we observed that the wettability of the porous medium changed from water-wet to mixed-wet. Overall, we demonstrate a micro-CT imaging and analysis workflow to quantify asphaltene deposition, permeability reduction and wettability change which can be used for reservoir characterisation and remediation.

Topics & Concepts

AsphalteneWettingPermeability (electromagnetism)Materials sciencePorous mediumHeptaneChemical engineeringRelative permeabilityPrecipitationPorosityComposite materialChemistryOrganic chemistryMeteorologyEngineeringMembranePhysicsBiochemistryPetroleum Processing and AnalysisHydrocarbon exploration and reservoir analysisEnhanced Oil Recovery Techniques