Tuning of the height of energy barrier between locally-excited and charge transfer states by altering the fusing position of<i>o</i>-carborane in phenylnaphthalene
Junki Ochi, Takumi Yanagihara, Kazuo Tanaka, Yoshiki Chujo
Abstract
Two types of o -carborane-based regioisomers fused by a phenylnaphthalene ring were synthesized. They showed different optical properties depending on the fused position.
Topics & Concepts
Structural isomerCarboraneExcited statePosition (finance)Charge (physics)Ring (chemistry)ChemistryChemical physicsComputational chemistryAtomic physicsMaterials scienceCrystallographyStereochemistryMolecular physicsOptoelectronicsPhysicsOrganic chemistryQuantum mechanicsEconomicsFinanceBoron Compounds in ChemistryLuminescence and Fluorescent MaterialsRadioactive element chemistry and processing