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Electrochemical detection of mercuric(<scp>ii</scp>) ions in aqueous media using glassy carbon electrode modified with synthesized tribenzamides and silver nanoparticles

Aalia Manzoor, Tayyaba Kokab, Anam Nawab, Afzal Shah, Humaira M. Siddiqi, Asma Iqbal

2022RSC Advances23 citationsDOIOpen Access PDF

Abstract

-ABA) by amidation reaction. Structural characterization of the synthesized compounds was done through spectroscopic techniques (FT-IR and NMR). The synthesized tribenzamides along with silver nanoparticles were used for modification of a glassy carbon electrode. Square wave anodic stripping voltammetry was carried out to test the performance of the modified electrode for mercuric ion detection. The designed sensor was found to demonstrate the qualities of sensitivity, selectivity, reproducibility and anti-interference ability. The sensing platform helped in detecting femtomolar concentrations of mercuric ions which are much below the level declared toxic by the World Health Organization.

Topics & Concepts

ElectrochemistryAqueous mediumElectrodeAqueous solutionIonNanoparticleGlassy carbonCarbon fibersSilver nanoparticleInorganic chemistryChemistryMaterials scienceNuclear chemistryChemical engineeringNanotechnologyCyclic voltammetryOrganic chemistryPhysical chemistryComposite numberEngineeringComposite materialElectrochemical Analysis and ApplicationsMercury impact and mitigation studiesMolecular Sensors and Ion Detection
Electrochemical detection of mercuric(<scp>ii</scp>) ions in aqueous media using glassy carbon electrode modified with synthesized tribenzamides and silver nanoparticles | Litcius