Photosensitizing metal covalent organic framework with fast charge transfer dynamics for efficient CO<sub>2</sub> photoreduction
Wang‐Kang Han, Jiayu Li, Ruo‐Meng Zhu, Min Wei, Shilin Xia, Jiaxing Fu, Jinfang Zhang, Huan Pang, Ming‐De Li, Zhi‐Guo Gu
Abstract
and 97.7% selectivity. The femtosecond transient absorption spectroscopy combined with theoretical calculations uncovered the fast charge-transfer dynamics occurring between the photoactive and catalytic centers, providing a comprehensive understanding of the photocatalytic mechanism. This work offers in-depth insight into the design of MCOF-based photocatalysts for solar energy utilization.
Topics & Concepts
PhotochemistryCovalent bondCharge (physics)CatalysisChemistryMetalNanotechnologyMaterials sciencePhysicsOrganic chemistryQuantum mechanicsAdvanced Photocatalysis TechniquesCovalent Organic Framework ApplicationsPerovskite Materials and Applications