Application of electrospun N-doped carbon dots loaded cellulose acetate membranes as cationic dyes adsorbent
Stefania Mottola, Gianluca Viscusi, Hebat‐Allah S. Tohamy, Mohamed El-Sakhawy, Giuliana Gorrasi, Iolanda De Marco
Abstract
This work aims to apply carbon quantum dots (CQDs) from agriculture cellulosic waste (agro wastes), produced via an economically and eco-friendly single-step method, to be used into cellulose acetate composite microfibrous membranes as an innovative solution specifically designed to adsorb methylene blue (MB) and other cationic dyes that are present in various water effluents. Batch adsorption tests were conducted, with variations in contact time (1–24 h), initial MB concentration (25–300 ppm), and adsorbent doses (1–20 g/L). The maximum adsorption capacity of the membrane was 198 mg/g with an initial concentration of 300 ppm at 298 K. Thermodynamic parameters showed that the process is endothermic. Equilibrium experimental data for MB adsorption onto electrospun adsorbent were fitted using different isothermal models, with the Freundlich model showing the best fit. The pseudo-second-order model accurately described the kinetic data with high reliability (R 2 > 0.99), and the calculated adsorption capacity was very close to the experimental data. N-CQDs loaded membranes were also tested for removing methyl violet and rhodamine B, demonstrating remarkably high dye removal efficiency. The underlying adsorption mechanism was also reported. Finally, it is worth mentioning that composite adsorbents can be efficiently applied to actual industrial cases because of the possibility of reusing them, opening the route to the fabrication of novel and highly performant adsorbents. These findings underscore N-CQDs’ effectiveness in enhancing pollutant removal efficiency from wastewater, highlighting their environmental benefits and promoting a more sustainable approach to water treatment. Therefore, the prepared adsorbent, showing excellent adsorption performance, places them among adsorbents for practical applications in wastewater purification. • Cellulose acetate/N-doped carbon quantum dots are successfully electrospun. • A novel system for adsorption of methylene blue was fabricated. • The effect of different parameters on the dye adsorption was investigated. • Removal efficiencies of rhodamine B and methyl violet were even evaluated.