Photoinduced ligand-to-iron charge transfer enabled C(sp<sup>3</sup>)–H phosphorylation of hydrocarbons
Wei Shi, Ping-Fu Zhong, Xu-Kuan Qi, Chao Yang, Lin Guo, Wujiong Xia
Abstract
An iron-catalyzed C(sp 3 )–H phosphorylation reaction enabled by a photoinduced ligand-to-metal charge transfer (LMCT) process is herein reported.
Topics & Concepts
Ligand (biochemistry)ChemistryPhosphorylationCharge (physics)PhotochemistryMetalOrganic chemistryReceptorBiochemistryPhysicsQuantum mechanicsCatalytic C–H Functionalization MethodsFluorine in Organic ChemistryOrganoboron and organosilicon chemistry